杩戞棩锛屾垜闄㈣秴鏀寲鑱氬悎鐗╁洟闃熷紶閬撴椽鏁欐巿鑱斿悎涓浗绉戝鎶€鏈ぇ瀛﹀紶瀹忎繆鏁欐巿銆佹境澶у埄浜氬ⅷ灏旀湰澶у鑻楀瓱娌虫暀鎺堢瓑鍦ㄤ簹绾崇背缁村害鎻ず瓒呮敮鍖栫幆姘ф爲鑴傚寮哄闊ф満鐞嗘柟闈㈠彇寰楁柊鐨勭爺绌惰繘灞曪紝鐮旂┒鎴愭灉浠?/span>鈥淯ltra-strong and high-tough thermoset epoxy resins from hyperbranched topological structure and subnanoscaled free volume鈥?/span>涓洪鍙戣〃浜庡浗闄呴《绾ф湡鍒娿€?/span>advanced materials銆嬶紙if=29.4锛夈€傚闄㈢澹爺绌剁敓鍒樻涓鸿鏂囩涓€浣滆€咃紝寮犻亾娲暀鎺堛€佸紶瀹忎繆鏁欐巿鍜岃嫍瀛熸渤鏁欐巿涓鸿鏂囩殑鍏卞悓閫氳浣滆€咃紝涓崡姘戞棌澶у涓鸿鏂囩殑绗竴閫氳鍗曚綅銆?/span>
鍥?/span>1. bn/dgeba鍏辫仛鐗╃殑澧炲己澧為煣鏈哄埗
鐜哀鏍戣剛鍏锋湁浼樺紓鐨勮€愯厫铓€鎬ц兘銆佹満姊版€ц兘鍜屽伐鑹烘€ц兘绛夌壒鐐癸紝琚箍娉涘簲鐢ㄤ簬鑸┖鑸ぉ銆侀鐢电瓑棰嗗煙銆傜劧鑰岀幆姘ф爲鑴傜殑鍙戝睍渚濈劧闈复鐫€寮哄害鍜岄煣鎬х殑鐭涚浘銆佸浐鍖栦骇鐗╅毦浠ラ檷瑙ｅ拰寰幆鍒╃敤绛夐毦棰橈紝闄愬埗浜嗗叾杩涗竴姝ョ殑骞挎硾搴旂敤銆備负姝わ紝寮犻亾娲暀鎺堝洟闃熷皢瓒呮敮鍖栨嫇鎵戠粨鏋勫紩鍏ョ幆姘ф爲鑴備腑锛屽厛鍚庡湪瓒呮敮鍖栫幆姘ф爲鑴傜殑鏋勭瓚涓庣粨鏋勮皟鎺э紙angew chem, 2022, 61, e202211713; 2021, 60, 331锛?/span>chem eng j: 2018, 334, 1371; 2020, 387,124071锛夈€佺幆姘ф爲鑴傜殑楂樻晥澧炲己涓庡闊э紙macromolecules, 2022, 55, 595; chem eng j: 2023, 465, 142998; 2023, 471, 144329; prog mater sci 2022, 130, 100977锛夈€佷互鍙婄幆姘ф爲鑴傞珮鏁堥檷瑙ｄ笌鍥炴敹(nat sustain, 2020, 3, 29; acs macro lett, 2021, 10, 1113; macromolecules, 2023, 56, 5290)绛夋柟闈㈠彇寰椾簡绯诲垪鎴愭灉銆傜劧鑰岋紝濡備綍閫氳繃璋冭妭瓒呮敮鍖栧垎瀛愮殑鎷撴墤缁撴瀯杩涗竴姝ラ珮鏁堣皟鎺х幆姘ф爲鑴傜殑寰缂洪櫡锛屼粠鑷敱浣撶н灏哄涓庡垎甯冭搴︽潵鐞嗚в鍜屾彮绀哄崗鍚屽寮哄闊ф満鐞嗕緷鐒舵槸涓€涓法澶х殑鎸戞垬銆?/span>
鏈伐浣滀腑锛屼綔鑰呭埄鐢ㄧ偣鍑诲寲瀛︽妧鏈皢閰颁簹鑳虹粨鏋勫紩鍏ョ幆姘ф爲鑴備腑锛屽埗澶囦簡涓€绯诲垪鎷撴墤缁撴瀯鍙帶鐨勮秴鏀寲鑱氶叞浜氳兒鐜哀鏍戣剛锛岃鐜哀鏍戣剛鑳芥樉钁楀悓鏃舵彁楂橀€氱敤鐜哀鏍戣剛锛?/span>dgeba锛夌殑寮哄害鍜岄煣鎬с€傞€氳繃姝ｇ數瀛愭巩娌″鍛借氨瀛︽妧鏈缁嗙爺绌跺苟鎻ず浜嗕簹绾崇背绾ц嚜鐢变綋绉昂瀵镐笌鍒嗗竷鐨勯檷浣庡拰鑷村瘑鍖栨満鍒讹紝鍗忓悓鎻愬崌鏍戣剛鐨勫己搴﹀拰闊ф€с€傝鐮旂┒涓虹幆姘ф爲鑴傜殑澧炲己澧為煣鏈哄埗鎻愪緵浜嗘柊鐨勭悊瑙ｅ拰璁よ瘑锛屼负楂樻€ц兘鍙檷瑙ｇ幆姘ф爲鑴傜殑璁捐寮€鍙戞彁渚涗簡鏂扮殑鏂规硶涓庨€斿緞銆?/span>
鏂囩珷淇℃伅锛?/span>xin liu, huanghu wu, wei xu, yu jiang, junheng zhang, bangjiao ye, hongjun zhang*, sufang chen, menghe miao*, daohong zhang*. ultra-strong and high-tough thermoset epoxy resins from hyperbranched topological structure and subnanoscaled free volume. advanced materials, 2023, doi: 10.1002/adma.202308434.
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