杩戞棩锛屾垜闄㈣秴鏀寲鑱氬悎鐗╁洟闃熷紶閬撴椽鏁欐巿鍜屽瀹囧壇鏁欐巿鍦ㄨ秴鏀寲鑱氬悎鐗╁井瑙傜粨鏋勭簿鍑嗚皟鎺ф柟闈㈠彇寰楁柊鐨勭爺绌惰繘灞曪紝鐩稿叧鎴愭灉浠モ€?span lang="en-us">one-pot structure-controlled synthesis of hyperbranched polymers by a "latent" inimer strategy based on diels-alder chemistry鈥?/span>涓洪锛屽彂琛ㄥ湪鍥介檯钁楀悕鏈熷垔銆婂痉鍥藉簲鐢ㄥ寲瀛︺€?span lang="en-us">(angew chem int ed 10.1002/anie.202211713) 涓娿€傚寲鏉愬闄㈢澹爺绌剁敓鏉ㄨ兘鍜屽瀹囧壇鏁欐巿涓鸿鏂囧叡鍚岀涓€浣滆€咃紝寮犻亾娲暀鎺堝拰濮滃畤鍓暀鎺堜负閫氳浣滆€咃紝涓崡姘戞棌澶у涓哄敮涓€閫氫俊缃插悕鍗曚綅銆?/span>
瓒呮敮鍖栬仛鍚堢墿浣滀负涓€绉嶉珮搴︽敮鍖栨嫇鎵戠粨鏋勭殑鑱氬悎鐗╋紝鍥犲叾浼樺紓鐨勬憾瑙ｆ€с€佷綆绮樺害鍜屽ぇ閲忔湯绔熀鍥㈢瓑浼樼偣鑰屽湪鑽墿杞戒綋銆佺撼绫虫潗鏂欏強鍒嗗瓙浼犳劅绛夐鍩熸湁鐫€閲嶈鐨勫簲鐢ㄥ墠鏅紝瓒呮敮鍖栬仛鍚堢墿鐨勫井瑙傜粨鏋勫鍏舵€ц兘銆佹€ц川鐨勫奖鍝嶆樉钁楋紝鍥犳寰缁撴瀯鐨勭簿鍑嗚皟鎺т竴鐩存槸瓒呮敮鍖栬仛鍚堢墿棰嗗煙鐨勫法澶ф寫鎴樸€傚洟闃熷厛鍚庡疄鐜颁簡瓒呮敮鍖栬仛鍚堢墿鐨勫畼鑳藉洟璋冩帶锛?span lang="en-us">chem eng j: 2018, 343, 283, 2018,334,1371, 2020,387,124071锛夈€佸寲瀛︾粍鎴愬拰楠ㄦ灦缁撴瀯璋冩帶锛?span lang="en-us">nat sustain2020, 3, 29锛?span lang="en-us">green chem: 2020, 22, 4187, 2022,doi: 10.1039/d2gc01541b锛?span lang="en-us">chem eng j 2020, 281, 122719锛?span lang="en-us">polymer 2019, 164, 154锛?span lang="en-us">prog org coat 2019, 134, 189锛夈€備絾鎷撴墤缁撴瀯绮惧噯璋冩帶闅惧害杈冨ぇ锛屽厛鍚庣爺绌朵簡鐐瑰嚮鍖栧銆侀€愭缂╄仛鍜岀姘㈠姞鎴愮瓑鎶€鏈紙prog org coat: 2016, 101,178,2019, 127, 157, 2022,165,106735; acs macro lett 2021, 10, 1113锛夋潵璋冩帶鎷撴墤缁撴瀯锛岃鐮旂┒宸ヤ綔鍙戝睍浜嗕竴绉嶅熀浜?span lang="en-us">diels-alder锛?span lang="en-us">d-a锛夊姩鎬佸寲瀛︾殑鈥?/span>涓€閿呮硶鈥?/span>璋冩帶瓒呮敮鍖栬仛鍚堢墿鎷撴墤缁撴瀯鐨勬柊绛栫暐锛堝浘1a锛夛紝璇ユ柟娉曞€熷姪d-a鍔ㄦ€佸叡浠烽敭鐨勫彲鎺ф€э紝浠庡弽搴旀俯搴﹀拰鍘熸枡鐨勭珛浣撳寲瀛︾粨鏋勪袱涓柟闈㈠疄鐜颁簡瓒呮敮鍖栬仛鍚堜骇鐗╂嫇鎵戠粨鏋勭殑绮惧噯璋冩帶锛堝浘1b锛夈€?/span>
鍥?/span>1.diels-alder鍔ㄦ€佸寲瀛﹀彲鎺у埗澶囩瓥鐣ワ紙a锛夊拰閫氳繃鍙嶅簲娓╁害鍜屽師鏂欑殑绔嬩綋鍖栧缁撴瀯璋冩帶瓒呮敮鍖栬仛鍚堜骇鐗╂嫇鎵戠粨鏋?/span>(b)鐨勫師鐞嗗浘.
鏈伐浣滈鍏堟瀯寤轰竴绉嶅惈鍛嬪杻淇濇姢鐨勯┈鏉ラ叞浜氳兒鍩哄洟锛?span lang="en-us">fmi锛夌殑鈥?/span>闅愭€?span lang="en-us">鈥?/span>寮曞彂鍗曚綋锛屼笌鐢插熀涓欑儻閰哥敳閰€氳繃鑷缉鍚堜箼鐑熀鍏辫仛锛?span lang="en-us">scvcp锛夊悎鎴愯秴鏀寲鑱氱敳鍩轰笝鐑吀鐢查叝銆?span lang="en-us">鈥?/span>闅愭€?span lang="en-us">鈥?/span>寮曞彂鍗曚綋閫氳繃閫?span lang="en-us">d-a鍙嶅簲閲婃斁鍑洪┈鏉ラ叞浜氳兒鍩哄洟锛?span lang="en-us">mi锛夎繘鑰岃浆鍖栦负鈥?/span>鏄炬€?span lang="en-us">鈥?/span>寮曞彂鍗曚綋骞跺弬涓庤仛鍚堛€傞€氳繃璋冭妭鈥?/span>闅愭€?span lang="en-us">鈥?/span>寮曞彂鍗曚綋涓?span lang="en-us">d-a鐜姞鎴愮粨鏋勫崟鍏冪殑绔嬩綋鍖栧缁撴瀯鍜岃仛鍚堝弽搴旀俯搴︼紝鍙湁鏁堣皟鎺ч€?span lang="en-us">d-a鍙嶅簲閫熺巼锛岃繘鑰岃皟鑺?span lang="en-us">mi鍩哄洟鐨勯噴鏀鹃€熺巼鍙婅仛鍚堝弽搴旈€熺巼锛屽疄鐜板瓒呮敮鍖栬仛鍚堢墿寰缁撴瀯鐨勭簿鍑嗚皟鎺с€備负浜嗘槑纭皟鎺ф満鍒讹紝浣滆€呴€氳繃鐞嗚璁＄畻鑾峰緱浜嗚秴鏀寲鑱氬悎鐗╂敮鍖栧害涓庡崟浣撹浆鍖栫巼銆?span lang="en-us">mi瀹樿兘鍥㈣浆鍖栫巼涔嬮棿鐨勫叧绯伙紝璁＄畻鍑虹殑涓嶅悓鍙嶅簲鏉′欢涓嬬殑鐞嗚鏀寲搴︿笌鑱氬悎浜х墿鐨勫疄闄呮敮鍖栧害缁撴灉姣旇緝鍚诲悎锛堝浘2锛夛紝璇佸疄浜嗘敮鍖栧害鎷撴墤缁撴瀯鐨勭簿鍑嗚皟鎺с€?/span>
鍥?/span>2.杞寲鐜囥€佽仛鍚堥€熺巼姣?/span>r銆佺悊璁烘敮鍖栧害锛堣櫄绾匡級鍜屽疄闄呮敮鍖栧害锛堝疄绾匡級闅忓弽搴旀俯搴︾殑鍙樺寲鏇茬嚎锛?/span>a锛変互鍙婄悊璁烘敮鍖栧害锛堣櫄绾匡級鍜屽疄闄呮敮鍖栧害锛堝疄绾匡級闅忓弽搴旀椂闂寸殑鍙樺寲鏇茬嚎(b).
杩涗竴姝ュ埄鐢ㄥ彲缂栫▼娓╁害绛栫暐锛堢▼搴忔帶娓╂妧鏈級锛屼綔鑰呰繕瀹炵幇浜嗏€滀竴閿呮硶鈥濇瀯寤烘槦鍨嬪強闀块摼瓒呮敮鍖栫瓑澶嶆潅鎷撴墤缁撴瀯鐨勮仛鍚堢墿锛堝浘3锛夈€傚熀浜庤楂樻晥鍜屾櫘閫傜殑鍘熺悊锛屽彲鏈涙嫇灞曞皢鍏朵粬涓嶅悓绫诲瀷鐨勩€佸弽搴旀潯浠舵洿涓烘俯鍜岀殑鍔ㄦ€佸寲瀛﹂敭鐢ㄤ簬璋冩帶瓒呮敮鍖栬仛鍚堢墿鐨勬嫇鎵戠粨鏋勩€?/span>
鍥?span lang="en-us">3. 绋嬪簭鎺ф俯鎶€鏈埗澶囨槦鍨嬪強闀块摼瓒呮敮鍖栨嫇鎵戠粨鏋?span lang="en-us">.
寮犻亾娲暀鎺堥琛旂殑瓒呮敮鍖栬仛鍚堢墿鍥㈤槦鏄牎瀛︽湳鍥㈤槦锛屽叆閫変簡婀栧寳鐪佽嚜鐒剁瀛﹀垱鏂扮兢浣撱€佸浗瀹舵皯濮斿垱鏂板洟闃熷拰婀栧寳鐪佸弻鍒涙垬鐣ュ洟闃燂紝渚濇墭浜庝腑鍗楁皯鏃忓ぇ瀛﹀寲瀛︿笌鏉愭枡绉戝瀛﹂櫌銆佸偓鍖栬浆鍖栦笌鑳芥簮鏉愭枡鍖栧鏁欒偛閮ㄩ噸鐐瑰疄楠屽鍜岃秴鏀寲鑱氬悎鐗╁悎鎴愪笌搴旂敤鎶€鏈箹鍖楃渷宸ョ▼鐮旂┒涓績锛岄暱鏈熶粠浜嬭秴鏀寲鑱氬悎鐗╁悎鎴愬強搴旂敤鐮旂┒锛屽洟闃熶富鎸佲€滆秴鏀寲鑱氬悎鐗┾€濋鍩熺殑鍥藉鑷劧绉戝鍩洪噾椤圭洰10浣欓」銆佺渷閲嶅ぇ閲嶇偣鍜屼紒涓氬鎵橀」鐩?span lang="en-us">30浣欓」锛岃幏鎺堟潈鍥介檯銆佸浗瀹跺彂鏄庝笓鍒?span lang="en-us">70浣欎欢銆傚疄鐜拌秴鏀寲鑱氬悎鐗╃郴鍒椾骇鍝佺殑浜т笟鍖栵紝寤烘垚鍥藉唴鏈€澶х殑骞翠骇鍗冨惃绾ц秴鏀寲鑱氬悎鐗╃敓浜хず鑼冪嚎锛屼负鍥藉唴200浣欐墍楂樻牎鍜岀鐮旈櫌鎵€鎻愪緵瓒呮敮鍖栬仛鍚堢墿鐮旂┒绫讳骇鍝侊紝涓哄浗鍐呭宸ョ▼濉戞枡鍔犲伐浼佷笟渚涘簲楂樻€ц兘鐨勮妭鑳藉姞宸ュ姪鍓傚拰鍏抽敭鎶€鏈紝淇冭繘浜嗗浗鍐呴珮鍒嗗瓙鏉愭枡鐨勫仴搴峰彂灞曘€傞儴鍒嗘垚鏋滆幏涓浗鐭虫补鍜屽寲瀛﹀伐涓氳仈鍚堜細绉戝鎶€鏈彂鏄庡涓€绛夊2椤广€佹箹鍖楃渷绉戝鎶€鏈彂鏄庡涓€绛夊1椤广€傝繎鍑犲勾鍥㈤槦鍦ㄨ秴鏀寲鑱氬悎鐗╁悎鎴愪笌缁撴瀯璋冩帶锛?span lang="en-us">prog mater sci 2022 130,100977锛?span lang="en-us">angew chem, 2021, 60, 331; chem eng j: 2018, 343,283, 2018, 334,1371, 2020, 281,122719; compos part b-eng, 2019, 160, 615锛夊拰瓒呮敮鍖栫幆姘ф爲鑴傚強鍏跺鍚堟潗鏂欑殑寰幆鍒╃敤锛?span lang="en-us">nat sustain, 2020, 3, 29锛?span lang="en-us">acs macro lett, 2021, 10, 1113; macromolecules 2022, 55, 595锛?span lang="en-us">compos part b-eng: 2020, 196, 108109, 2020, 192, 108005锛?span lang="en-us">green chem: 2020, 22, 4187,2022, doi: 10.1039/d2gc01541b锛夌瓑棰嗗煙鑾峰緱浜嗕竴浜涙垚鏋滐紝淇冭繘浜嗙浉鍏抽鍩熷揩閫熷仴搴峰彂灞曘€?/span>
鏂囩珷淇℃伅锛?span lang="en-us">neng yang#, yu jiang#,*, qinwen tan, jiahui ma, dezhi zhan, zhaohong wang, xin wang, daohong zhang*, and nikos hadjichristidis. one-pot structure-controlled synthesis of hyperbranched polymers by a "latent" inimer strategy based on diels-alder chemistry. angew. chem. int. ed., 2022, doi:10.1002/anie.202211713.
https://onlinelibrary.wiley.com/doi/10.1002/anie.202211713